

The chemical industry remains one of the world’s largest industrial energy consumers and a major source of direct industrial CO₂ emissions due to the thermodynamic and kinetic requirements of its energy-intensive processes and heavy reliance on fossil-based hydrocarbons. A more sustainable approach is to replace fossil feedstocks with bio-derived molecules and to develop more energy-efficient reactions, which often rely on heterogeneous catalysis. An example of this is the oxidative dehydrogenation (ODH) of bio-based or conventional ethanol over iron-molybdate catalysts, which provides a sustainable alternative to the large-scale production of acetaldehyde using the homogeneous Wacker-Höchst ethylene oxidation process.

Further investigation of gas-phase concentrations and temperature in the boundary layer above the solid catalyst is required to characterize, understand, and optimize the reaction pathways, since key transport and kinetic interactions occur in this layer
A dual-track Raman spectrometer, developed specifically for this application, is employed as a diagnostic tool to measure the local gas-phase composition and temperature in a custom-designed, 3D catalytic flow channel. To provide a more comprehensive understanding of the complex interactions between the gas phase, transport, and surface chemistry, gas-phase measurements are supplemented by (sub-)surface-sensitive techniques, such as solid-phase Raman spectroscopy and infrared thermography of the catalytic surface.
The chemical industry remains one of the world’s largest industrial energy consumers and a major source of direct industrial CO₂ emissions due to the thermodynamic and kinetic requirements of its energy-intensive processes and heavy reliance on fossil-based hydrocarbons. A more sustainable approach is to replace fossil feedstocks with bio-derived molecules and to develop more energy-efficient reactions, which often rely on heterogeneous catalysis. An example of this is the oxidative dehydrogenation (ODH) of bio-based or conventional ethanol over iron-molybdate catalysts, which provides a sustainable alternative to the large-scale production of acetaldehyde using the homogeneous Wacker-Höchst ethylene oxidation process.

Further investigation of gas-phase concentrations and temperature in the boundary layer above the solid catalyst is required to characterize, understand, and optimize the reaction pathways, since key transport and kinetic interactions occur in this layer
A dual-track Raman spectrometer, developed specifically for this application, is employed as a diagnostic tool to measure the local gas-phase composition and temperature in a custom-designed, 3D catalytic flow channel. To provide a more comprehensive understanding of the complex interactions between the gas phase, transport, and surface chemistry, gas-phase measurements are supplemented by (sub-)surface-sensitive techniques, such as solid-phase Raman spectroscopy and infrared thermography of the catalytic surface.

